Learning Notebook - David Rostcheck
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Sigma and pi bonds are types of covalent bonds that differ in the overlapping of atomic orbitals. Covalent bonds are formed by the overlapping of atomic orbitals. Sigma bonds are a result of the head-to-head overlapping of atomic orbitals whereas pi bonds are formed by the lateral overlap of two atomic orbitals. Various bond parameters such as bond length, bond angle, and bond enthalpy depend on the way the overlapping of atomic orbital takes place. This overlap occurs in two major ways, giving rise to two primary types of covalent bonds, i.e. sigma and pi bonds.
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